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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 5
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Articles

Oxidation of 1,4-disubstituted-1,2,3-triazoles with H2O2-CF3CO2H: efficient synthesis of 1,2,3-triazole 3-oxides

Norberto González-MojicaCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information
,
Leticia Almazán-SánchezCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information
,
Jesús G. García-TorresCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information
,
Ivette Santana-MartinezCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information
,
Diego Martínez-OteroCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information
,
Miguel A. Sánchez-CarmonaCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoView further author information
&
Erick Cuevas-YañezCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Toluca, Estado de México, MexicoCorrespondence[email protected]
ORCID Iconhttp://orcid.org/0000-0002-9437-637XView further author information
ORCID Icon show all
Pages 679-687 | Received 10 Aug 2018, Accepted 03 Jan 2019, Published online: 06 Feb 2019
 
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Abstract

A collection of 1,2,3-triazole-3-oxides was obtained from oxidation of the corresponding 1,4-disubstituted-1,2,3-triazoles mediated by a H2O2-CF3CO2H system through a simple protocol in good yields showing high efficiency.

Graphical Abstract

Acknowledgments

The authors would like to thank N. Zavala, A. Nuñez, and L. Triana for the technical support.

Additional information

Funding

Financial support from SIEA-UAEMEX (Project No. 4326/2017/C1) and CONACYT (Project No. 135053) is gratefully acknowledged.

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