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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 8
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Articles

Addition-elimination of nitroalkanes to 3-phenacylideneoxindoles—direct method for the synthesis of 3-alkenylphenacylidene-oxindoles

Yu-Xuan FuSchool of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, People’s Republic of ChinaView further author information
,
Shan-Shan HuSchool of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, People’s Republic of ChinaView further author information
,
Shao-Yi LiSchool of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, People’s Republic of ChinaView further author information
&
Xiao-Juan LiSchool of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, People’s Republic of ChinaCorrespondence[email protected]
View further author information
Pages 1067-1075 | Received 15 Dec 2018, Accepted 21 Feb 2019, Published online: 26 Mar 2019
 
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Abstract

The first addition-elimination of nitroalkanes to 3-phenacylideneoxindoles was developed, affording the corresponding 3-alkenylphenacylidene-oxindoles with high yields.The addition-elimination mechanism of 3-phenacylideneoxindoles with nitroalkanes and removable NO2 group in concert guarantees the high regioselectivity.

GRAPHICAL ABSTRACT

Additional information

Funding

This work was financial supported by National Natural Science Foundation of China (Grants 21302161).

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