Effective recovery of bitumen from Jordanian tar sand using several extraction methods

ABSTRACT

The study aims to characterize the structural features of Jordanian tar sand using analytical techniques including (FTIR, ultimate and proximate analysis, TGA, XRD, and XRF). The tar sand shows a low content of volatile matter (bitumen) with significant nitrogen content. The bitumen contains a high proportion of aliphatic hydrocarbons of which high content of it attached to oxygen atom. The minerals were mainly quartz and low concentration of carbonate with noticeable content of sulfite and potassium oxide from XRF. The recovery of bitumen was evaluated using three different extraction techniques: solvent extraction methods (ultrasound-assisted extraction, non-aqueous extraction) and thermal pyrolysis using the Fischer assay apparatus. The non-aqueous solvent extraction method gave the highest bitumen recovery using toluene as a solvent; however, the high-temperature Fischer assay method provided a low recovery. The extracted bitumen under the optimum condition was characterized using NMR, elemental analysis, and GC-MS analysis. The oil products from tar sand showed a high concentration of oxygen and noticeable concentration of sulfur atoms. The ¹H-NMR revealed a high content of aliphatic hydrocarbons in good agreement with raw tar sand characteristics. The identified compounds in the GC-MS where mainly substituted with oxygen atom in the form of alcohols and ethers.

GRAPHICAL ABSTRACT

KEYWORDS:

• Tar sand
• non-aqueous extraction
• ultrasonic method
• thermal pyrolysis
• bitumen
• recovery
• GC-MS
• elemental analysis

Acknowledgements

We thank the Deanship of Scientific Research, The University of Jordan for financial support, the Natural Resources Authority of Jordan for the supply of the Tar Sand sample.

Disclosure statement

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Correction Statement

This article has been republished with minor changes. These changes do not impact the academic content of the article.

Additional information

Funding

The work was supported by the Deanship of Scientific Research, University of Jordan, Jordan