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Original Articles

Solvent Extraction of Cadmium from Alkaline Cyanide Solutions with Quaternary Amines

Pages 37-46 | Received 21 Mar 1975, Accepted 01 Apr 1975, Published online: 02 Sep 2009
 

Abstract

Quaternary amines are unique in their ability to extract metal cyanides from highly alkaline solutions. Cadmium cyanide extracts essentially quantitatively at both the subnanogram and macro levels. Regeneration of the amine solvent is achieved by stripping the cadmium with sodium hydroxide, sodium hypochlorite, or alkaline or acidic formaldehyde solutions. Because they readily extract free cyanide as well as anionic metal cyano complexes, the high-molecular-weight quaternary amines show considerable promise for industrial pollution abatement applications.

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