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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 2
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Original Articles

Versatile Spirocyclic Glycine‐Based Nitrones and Their Highly Stereoselective 1,3‐Dipolar Cycloaddition

Shangli Cheng Chemistry Department, Wuppertal University, Wuppertal, GermanyCorrespondence[email protected]
,
Huimin Wu College of Pharmacy, Wuhan University, Wuhan, Hubei, China
&
Xianmin Hu College of Pharmacy, Wuhan University, Wuhan, Hubei, China
Pages 297-308 | Received 16 Mar 2006, Published online: 25 Jul 2007
 
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Abstract

A convenient and efficient method for the synthesis of novel spirocyclic nitrones prepared from glycine derivatives is reported. The 1,3‐cycloaddition reactions of the nitrones with alkenes lead to novel isoxazolidines in high yields and with excellent regio‐ and stereoselectivity.

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