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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 2
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Original Articles

Bromination of Some Aromatic Compounds with Potassium Bromide in the Presence of Benzyltriphenylphosphonium Peroxodisulfate

Hassan Tajik Department of Chemistry, Guilan University, Rasht, Iran; Persian Gulf University, Bushehr, IranCorrespondence[email protected] [email protected]
,
Iraj Mohammadpoor‐Baltork Department of Chemistry, College of Science, Isfahan University, Isfahan, Iran
&
Jalal Albadi Department of Chemistry, Guilan University, Rasht, Iran; Persian Gulf University, Bushehr, Iran
Pages 323-328 | Received 30 Mar 2006, Published online: 25 Jul 2007
 
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Abstract

A simple, efficient, and mild method for selective bromination of some activated aromatic compounds using potassium bromide in the presence of benzyltriphenylphosphonium peroxodisulfate in nonaqueous solution is reported. The results obtained revealed good to excellent selectivity between ortho and para positions of phenols and methoxyarenes.

Acknowledgment

We are thankful to the Guilan University and also the Persian Gulf University Research Councils for their partial support of this work.

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