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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 19
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Original Articles

Regioselective Photochemical and Microwave Mediated Monobromination of Aromatic Compounds using 2,4,4,6–Tetrabromo‐2,5‐cyclohexadienone

Neeraj Gupta Department of Chemistry, Centre for Advanced Studies in Chemistry, Punjab University, Chandigarh, India
,
Goverdhan L. Kad Department of Chemistry, Centre for Advanced Studies in Chemistry, Punjab University, Chandigarh, India
,
Vasundhara Singh Department of Applied Sciences, Punjab Engneering College, (Deemed University), Chandigarh, India
&
Jasvinder Singh Department of Chemistry, Centre for Advanced Studies in Chemistry, Punjab University, Chandigarh, IndiaCorrespondence[email protected]
Pages 3421-3428 | Received 05 Feb 2007, Published online: 05 Oct 2007
 
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Abstract

Bromination of different aromatic substrates have been described using 2,4,4,6‐tetrabromo‐2,5‐cyclohexadienone in conjunction with microwave and ultraviolet radiations. Important features of the work include high regioselectivity obtained in very short to moderate reaction time, atom economy, and recyclability of the reagent.

Acknowledgment

Authors are thankful to University Grant Commission (UGC) and Council of Scientific and Industrial Research (CSIR) New Delhi (India) for providing financial assistance.

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