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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 18
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Original Articles

Stereo‐ and Regioselective Thiolysis of 1,2‐Epoxides in Water

Barahman Movassagh Department of Chemistry, K. N. Toosi University of Technology, Tehran, Iran; Kermanshah Oil Refining Company, Kermanshah, IranCorrespondence[email protected]
&
Mohammad Soleiman‐Beigi Department of Chemistry, K. N. Toosi University of Technology, Tehran, Iran
Pages 3239-3244 | Received 04 Oct 2006, Published online: 10 Sep 2007
 
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Abstract

A simple, efficient, stereoselective, and highly regioselective procedure for the synthesis of β‐hydroxy sulfides by thiolysis of various 1,2‐epoxides in water as a solvent, using no catalyst and under very mild conditions, is described.

Acknowledgments

The K. N. Toosi University of Technology Research Council and Kermanshah Oil Refining Company are thanked for financial support of this work.

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