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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 21
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Original Articles

Convenient Synthesis of Aryl Ferrocenyl Ketone via Palladium‐Catalyzed Carbonylation Coupling

Dong Yang State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, China
,
Zenglu Liu Pharmacy College of Shanghai Jiao Tong University, Shanghai, China
,
Ying Li State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, China
&
Baohua Chen State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, ChinaCorrespondence[email protected]
Pages 3759-3765 | Received 16 Mar 2007, Published online: 19 Oct 2007
 
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Abstract

A series of aryl ferrocenyl ketones were prepared from iodoferrocene, phenylboronic acids, and CO via palladium‐catalyzed carbonylation coupling in a short time. The procedure was efficient and convenient and avoided formation of diacylated derivatives compared with currently available Friedel–Crafts acylation methodologies.

Acknowledgment

The authors are grateful to the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry.

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