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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 43, 2013 - Issue 20
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Original Articles

PCC-Promoted Dehydration of Aldoximes: A Convenient Access to Aromatic, Heteroaromatic, and Aliphatic Nitriles

S. Chandrappa Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, India
,
T. S. R. Prasanna Synthetic Polymer Laboratory, Department of Polymer Science and Technology, Sri Krisnadevaraya University, Anantapur, India
,
K. Vinaya Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, India
,
D. S. Prasanna Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, India
&
K. S. Rangappa Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, IndiaCorrespondence[email protected] ; [email protected]
Pages 2756-2762 | Received 07 Sep 2012, Published online: 08 Jul 2013
 
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Abstract

A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoximes using a PCC (pyridiniumchlorochromate) has been developed. A variety of aromatic, heteroaromatic, and aliphatic aldoximes are converted.

Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the full spectral details.

GRAPHICAL ABSTRACT

ACKNOWLEDGMENT

The authors are grateful to the University Grants Commission, Government of India, for financial support to K. S. R. under Project No. F. 31-143/2005(SR).

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