Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 46, 2016 - Issue 2
Submit an article Journal homepage
931
Views
22
CrossRef citations to date
0
Altmetric
Original Articles

Photoredox catalyst-mediated direct regioselective phosphonylation of indoles

Zijian ZhaoState Key Laboratory of Chemo/biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, China;Huaihua University, Huaihua, China
,
Zehui MinState Key Laboratory of Chemo/biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, China
,
Wanrong DongState Key Laboratory of Chemo/biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, ChinaCorrespondence[email protected] [email protected] [email protected]
,
Zhihong PengState Key Laboratory of Chemo/biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, China
&
Delie AnState Key Laboratory of Chemo/biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, China
Pages 128-133 | Received 02 Nov 2015, Published online: 19 Jan 2016
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

ABSTRACT

An efficient hetero-cross-dehydrogenative-coupling (hetero-CDC) reaction between N-protected indoles and phosphites to 2-indolyphosphites is described. The regioselective methodology took place in the presence of photo redox catalyst Ru(bpy)3(PF6)2 combined with oxygen as an clean oxidant when exposed to visible light, furnishing the 2-indolyphosphites as the exclusive products in moderate to good yields with good functional group tolerance. Moreover, the phosphonylation protocol was proved by the control reaction to proceed through the radical pathway.

GRAPHICAL ABSTRACT

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.