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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 46, 2016 - Issue 2
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Original Articles

Synthesis and reactivity of two new trichloromethyl substituted dihydroisoquinoline-derived oxaziridines

Rihab AydiLaboratory of Chemistry of Natural Products, Sfax University, Faculty of Science, Sfax, Tunisia
&
Majed KammounLaboratory of Chemistry of Natural Products, Sfax University, Faculty of Science, Sfax, TunisiaCorrespondence[email protected]
Pages 134-144 | Received 14 Jun 2015, Published online: 19 Jan 2016
 
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ABSTRACT

N-Alkyl oxaziridines may be used as reagents for the oxidation of sulfides in acid-promoted reactions. This article reports on a simple and efficient synthesis of two new trichloromethyl substituted dihydroisoquinoline oxaziridines, a new family of organic oxidizing agents. Their oxygen transfer capability with respect to sulfides as model substrates and in the absence of acid is investigated.

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