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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 46, 2016 - Issue 11
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Original Articles

Transition-metal-free synthesis of thiocyanato- or nitro-arenes through diaryliodonium salts

Xiao-Hua LiKey Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, China
,
Liang-Gui LiKey Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, China
,
Xue-Ling MoKey Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, China
&
Dong-Liang MoKey Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin, ChinaCorrespondence[email protected]
Pages 963-970 | Received 21 Feb 2016, Published online: 03 Jun 2016
 
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ABSTRACT

A transition-metal-free approach to facile synthesis of thiocyanato- and nitro-arenes was developed from KSCN (potassiumthiocyanate) or NaNO2 with diaryliodonium salts in good yields under mild conditions. The reaction was compatible with a variety of sensitive functional substituents such as halides and nitro and ester groups. The usefulness of arylation products has been realized.

GRAPHICAL ABSTRACT

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