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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 46, 2016 - Issue 23
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Original Articles

TBD-catalyzed cyanosilylation of aldehydes and ketones

S. MatsukawaDepartment of Science Education, Faculty of Education, Ibaraki University, Mito, Ibaraki, JapanCorrespondence[email protected]
&
J. KimuraDepartment of Science Education, Faculty of Education, Ibaraki University, Mito, Ibaraki, Japan
Pages 1947-1952 | Received 15 Aug 2016, Published online: 07 Oct 2016
 
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ABSTRACT

This study examines the catalytic efficacy of 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TBD) in the cyanosilylation of aldehydes and ketones. In an aldehyde reaction, the corresponding products were obtained at high yield using minimal TBD (0.01 mol%). TBD was similarly effective in various ketone reactions.

GRAPHICAL ABSTRACT

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