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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 17
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SYNTHETIC COMMUNICATIONS REVIEWS

Ligand-supported palladium-catalyzed cross-coupling reactions of (hetero) aryl chlorides

Efeturi Abraham OnoabedjeDepartment of Pure & Industrial Chemistry, University of Nigeria, Nsukka, Enugu State, NigeriaCorrespondence[email protected]
&
Uchechukwu Chris OkoroDepartment of Pure & Industrial Chemistry, University of Nigeria, Nsukka, Enugu State, Nigeria
Pages 2117-2146 | Received 11 Dec 2018, Published online: 30 May 2019
 
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Abstract

The introduction of electron rich and sterically hindered ligands has made otherwise inert aryl chlorides and hetero aryl chlorides viable coupling partners in palladium-catalyzed Suzuki-Miyaura, Sonogashira, Stille and other types of cross-coupling reactions. This review gives highlights of cross-coupling of aryl chlorides employing in situ generated palladium catalytic systems.

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