Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 9
Submit an article Journal homepage
1,222
Views
6
CrossRef citations to date
0
Altmetric
Articles

NHC-coordinated palladacycle catalyzed 1,2-addition of arylboronates to unactivated ketones

Ryo AkiyamaDepartment of Materials Science and Engineering, Graduate School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, Japan; View further author information
,
Mariko SugayaDepartment of Materials Science and Engineering, Graduate School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, Japan; View further author information
,
Hiraku ShinozakiDepartment of Applied Chemistry, School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, JapanView further author information
&
Tetsuya YamamotoDepartment of Applied Chemistry, School of Engineering, Tokyo Denki University, Adachi-ku, Tokyo, JapanCorrespondence[email protected]
View further author information
Pages 1193-1201 | Received 05 Feb 2019, Accepted 08 Mar 2019, Published online: 28 Mar 2019
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Palladium catalyzed intermolecular 1,2-addition of arylboronate to unactivated ketone was investigated. NHC-coordinated palladacycle 4c exhibited catalytic activity for the reactions and provided the corresponding tertiary alcohols and γ,γ-disubstituted γ-lactones in good to excellent yields.

Graphical Abstract

Additional information

Funding

This work was supported in part by the Research Institute for Science and Technology, Tokyo Denki University Grant Number Q16E-02.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.