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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 18
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Articles

Iron(III)-catalyzed direct synthesis of diphenylmethyl esters from 2-diphenylmethoxypyridine

Van Hieu TranDepartment of Nuclear Medicine, Molecular Imaging and Therapeutic Medicine Research Center, Chonbuk National University Medical School and Hospital, Jeonju54907, Republic of Korea; ;Research Institute of Clinical Medicine of Chonbuk, National University-Biomedical Research Institute of Chonbuk National University Hospital, Jeonju54907, Republic of KoreaView further author information
,
Minh Thanh LaDepartment of Nuclear Medicine, Molecular Imaging and Therapeutic Medicine Research Center, Chonbuk National University Medical School and Hospital, Jeonju54907, Republic of Korea; ;Research Institute of Clinical Medicine of Chonbuk, National University-Biomedical Research Institute of Chonbuk National University Hospital, Jeonju54907, Republic of KoreaView further author information
&
Hee-Kwon KimDepartment of Nuclear Medicine, Molecular Imaging and Therapeutic Medicine Research Center, Chonbuk National University Medical School and Hospital, Jeonju54907, Republic of Korea; ;Research Institute of Clinical Medicine of Chonbuk, National University-Biomedical Research Institute of Chonbuk National University Hospital, Jeonju54907, Republic of KoreaCorrespondence[email protected]
View further author information
Pages 2379-2387 | Received 15 Apr 2019, Published online: 20 Jun 2019
 
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Abstract

A highly efficient method has been developed for the synthesis of diphenylmethyl (DPM) esters from 2-diphenylmethoxypyridine. Various carboxylic acids readily reacted with 2-diphenylmethoxypyridine in the presence of FeCl3 as a catalyst to provide the desired DPM esters with high yields. The procedure is facile and enables effective synthesis of a variety of esters for the protection of carboxylic acids.

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Disclosure statement

No potential conflict of interest was reported by the authors.

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Funding

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education [2018R1D1A1B07047572]. Tran Van Hieu and La Minh Thanh were supported by the BK21 Plus program in the Chonbuk National University Medical School.

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