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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 51, 2021 - Issue 8
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Articles

Effects of new NHC derivatives as ligands in the Suzuki–Miyaura reaction

Ülkü Yılmaza Department of Engineering Basic Sciences, Faculty of Engineering and Natural Sciences, Malatya Turgut Özal University, Malatya, TurkeyCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0002-2806-4781
ORCID Icon &
Hasan Küçükbayb Department of Chemistry, Faculty of Science and Arts, İnönü University, Malatya, TurkeyORCID Iconhttps://orcid.org/0000-0002-7180-9486
ORCID Icon
Pages 1184-1196 | Received 26 Aug 2020, Published online: 08 Feb 2021
 
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Abstract

A series of NHC-derivative ligands was synthesized from bisbenzimidazole salts as the precursor of N-heterocyclic carbene with chalcogens, carbon disulfide, and phenyl isothiocyanate reagents. These new ligands were used in the Suzuki–Miyaura cross-coupling reaction in the presence of palladium(II) acetate. Particularly, it was observed a remarkable ligand activity with tellurourea (5).

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