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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 18
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Original Articles

ENANTIOSELECTIVE HYDROGENATION OF KETONE OXIME CATALYZED BY IR-DPAMPP COMPLEX

Yinong Xie Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China
,
Aiqiao Mi Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China
,
Yaozhong Jiang Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China
&
Hui Liu Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610 041, P. R. China
Pages 2767-2771 | Received 22 Sep 2000, Published online: 15 Aug 2006
 
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Abstract

A catalyst system, Ir(I)-DPAMPP-iodide, was found to be efficient in the asymmetric hydrogenation of ketone oxime with the highest enantioselectivity of 93% ee.

ACKNOWLEDGMENTS

We are grateful for the financial support from the National Science Foundation of China (No. 29790124 and 29972040).

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