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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 23
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Original Articles

INDIUM MEDIATED REDUCTIVE ACYLATIONS OF NITROARENES TOWARDS N,O-DIACYLATED N-ARYLHYDROXYLAMINES*

Byeong Hyo Kim Department of Chemistry, Kwangwoon University, Seoul, 139-701, South KoreaCorrespondence[email protected]
,
Jae Wook Cheong Department of Chemistry, Kwangwoon University, Seoul, 139-701, South Korea
,
Rongbi Han Department of Chemistry, Kwangwoon University, Seoul, 139-701, South Korea
,
Young Moo Jun Department of Chemistry, Kwangwoon University, Seoul, 139-701, South Korea
,
Woonphil Baik Department of Chemistry, Myong Ji University, Kyung Ki Do, South Korea
&
Byung Min Lee Korea Research Institute of Chemical Technology, Taejon, South Korea
Pages 3577-3586 | Received 25 Dec 2000, Published online: 16 Aug 2006
 
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Abstract

By applying indium, Ac2O, MeOH, and catalytic amount of InCl3 in CHCl3 solution, nitroarenes were transformed into N,O-diacylated N-arylhydroxylamines in moderate to excellent yields.

*Dedicated to Professor Jack W. Timberlake on the occasion of his 60th Birthday.

ACKNOWLEDGMENTS

This work was supported by the Brain Korea 21 project and partly by Kwangwoon University in the year 2000.

Notes

*Dedicated to Professor Jack W. Timberlake on the occasion of his 60th Birthday.

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