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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 23
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Original Articles

CLEAVAGE OF VINYL CARBON–SILICON BOND IN γ-TRIMETHYLSILYL ALLYLIC ALCOHOLS

M. I. Al-Hassan Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia
&
R. B. Miller Department of Chemistry, University of California, Davis, California, 95616, U.S.A.
Pages 3641-3645 | Received 01 May 2000, Published online: 16 Aug 2006
 
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Abstract

Cleavage of the vinyl carbon–silicon bond by fluoride ion requires a free hydroxyl group located in such a position that stable cyclic transition state can be attained.

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