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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 24
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Original Articles

[NO3)3Ce]3.H2IO6: AS A VERSATILE AND EFFICIENT REAGENT FOR CLEAVAGE OF CARBON–NITROGEN DOUBLE BONDS UNDER HETEROGENEOUS AND NON-AQUEOUS CONDITIONS

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Pages 3775-3779 | Received 20 Sep 2000, Published online: 09 Nov 2006
 

Abstract

Oximes, hydrazones and semicarbazones of benzylic aldehydes and ketones undergo facile cleavage to the corresponding carbonyl compounds by tris[tri-nitratocerium(IV)]paraperio- date, [(NO3)3Ce]3.H2IO6, in good to high yields.

ACKNOWLEDGMENTS

We are thankful to Gulian University Research Council for the partial support of this work.

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