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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 24
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Original Articles

ULTRASOUND PROMOTED SYNTHESIS OF β-HYDROXYESTERS BY REFORMATSKY REACTION USING INDIUM METAL

Phil Ho Lee Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea
,
Keukchan Bang Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea
,
Kooyeon Lee Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea
,
Sun-young Sung Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea
&
Sukbok Chang Department of Chemistry, Ewha Womans University, Seoul, 120-750, South Korea
Pages 3781-3789 | Received 20 Sep 2000, Published online: 09 Nov 2006
 
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Abstract

Ultrasound promoted Reformatsky reaction by the reaction of aldehydes or ketone with ethyl bromoacetate in the presence of indium metal afforded β-hydroxyesters in good to excellent yields under mild conditions.

ACKNOWLEDGMENTS

This work was supported by Korea Research Foundation Grant (KRF-99-005-D00048). The gas chromatograms were provided by GC facility, supported by Research Center for Advanced Mineral Aggregate Composite Products.

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