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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 2
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Original Articles

Selective Removal of Benzyl Carbonate Used as a Protecting Group in Carbohydrate Chemistry

Fouzi Mouffouk Laboratoire de Chimie Biomoléculaire, UMR 5032 Université Montpellier II–ENSCM, 8, rue de l'Ecole Normale, 34296, Montpellier, Cedex 05, France
,
Alain Morère Laboratoire de Chimie Biomoléculaire, UMR 5032 Université Montpellier II–ENSCM, 8, rue de l'Ecole Normale, 34296, Montpellier, Cedex 05, FranceCorrespondence[email protected]
,
Sébastien Vidal Laboratoire de Chimie Biomoléculaire, UMR 5032 Université Montpellier II–ENSCM, 8, rue de l'Ecole Normale, 34296, Montpellier, Cedex 05, France
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Alain Leydet Laboratoire de Chimie Biomoléculaire, UMR 5032 Université Montpellier II–ENSCM, 8, rue de l'Ecole Normale, 34296, Montpellier, Cedex 05, France
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Jean-Louis Montero Laboratoire de Chimie Biomoléculaire, UMR 5032 Université Montpellier II–ENSCM, 8, rue de l'Ecole Normale, 34296, Montpellier, Cedex 05, France
Pages 303-307 | Received 27 Feb 2003, Published online: 18 Oct 2011
 
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Abstract

It has been demonstrated that benzyl carbonate protecting group is orthogonal with tert-butyldimethylsilyl and (4-methoxy)trityl ethers. Moreover, benzyl carbonates can be selectively cleaved using aminolysis conditions.

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