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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 3
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Original Articles

Synthesis of Diaryl Ketones Catalyzed by Al2O3‐ZrO2/S2O82− Solid Superacid

Tong‐Shou Jin Department of Chemistry, College of Chemistry and Environmental Science, Hebei University, 88 He Zuo Road, Baoding, 071002, Hebei Province, P. R. ChinaCorrespondence[email protected]
,
Mi‐Na Yang Department of Chemistry, College of Chemistry and Environmental Science, Hebei University, 88 He Zuo Road, Baoding, 071002, Hebei Province, P. R. China
,
Guo‐Liang Feng Department of Chemistry, College of Chemistry and Environmental Science, Hebei University, 88 He Zuo Road, Baoding, 071002, Hebei Province, P. R. China
&
Tong‐Shuang Li Department of Chemistry, College of Chemistry and Environmental Science, Hebei University, 88 He Zuo Road, Baoding, 071002, Hebei Province, P. R. China
Pages 479-485 | Received 02 Jun 2003, Published online: 16 Aug 2006
 
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Abstract

The acylation of a variety of aromatic compounds with benzoyl chloride or its derivatives and catalytic amounts of Al2O3–ZrO2/S2O8 2− solid superacid affords the corresponding diaryl ketones in good to excellent yields 75–93% at appropriate temperature.

Acknowledgments

We wish to thank Natural Science Fund of China (29872011), Educational Ministry of China, Educational Department of Hebei Province (990104) and Science and Technology Commission of Hebei Province for support of this work.

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