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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 5
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Original Articles

Mild Diazo Transfer Reaction Catalyzed by Modified Clays

Renata de S. Rianelli Departamento de Química Orgânica, Instituto de Química, Universidade Federal Fluminense, Niterói, Rio de Janeiro, 24020‐150, Brazil
,
Maria Cecília B. V. de Souza Departamento de Química Orgânica, Instituto de Química, Universidade Federal Fluminense, Niterói, Rio de Janeiro, 24020‐150, Brazil
&
Vitor F. Ferreira Departamento de Química Orgânica, Instituto de Química, Universidade Federal Fluminense, Niterói, Rio de Janeiro, 24020‐150, BrazilCorrespondence[email protected]
Pages 951-959 | Received 04 Oct 2003, Published online: 20 Aug 2006
 
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Abstract

A very mild method for the preparation of various 2‐diazo‐1,3‐carbonyl compounds in the presence of environmentally attractive solid acids such as clays in a heterogeneous manner in moderate to good yield is reported.

Acknowledgments

Fellowships granted to RSR by CAPES and M.C.B.V.S. and V.F.F. by CNPq (Brazil) are gratefully acknowledged. This work was partially supported by CNPq (National Council of Research of Brazil) and FAPERJ.

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