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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 11
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Original Articles

Facile Preparation of α‐Acyloxyacetaldehyde, a Versatile Intermediate in the Synthesis of Antiviral Nucleosides

Jinfa Du Pharmasset, Inc., 1860 Montreal Road, Tucker, Georgia, 30084, USACorrespondence[email protected]
&
Kyoichi A. Watanabe Pharmasset, Inc., 1860 Montreal Road, Tucker, Georgia, 30084, USA
Pages 1925-1930 | Received 06 Jan 2004, Published online: 20 Aug 2006
 
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Abstract

This report describes a novel and simple method for the preparation of a versatile intermediate, α‐acyloxyacetaldehyde and its acetals, and its application to the synthesis of 4‐acetoxy‐2‐acyloxymethyl‐1,3‐oxathiolane, an important intermediate in the synthesis of biologically active nucleosides.

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