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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 11
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Original Articles

Immediate and Efficient Oxidative Deprotection of Dithioacetals to Carbonyl Compounds by Zinc Dichromate Trihydrate (ZnCr2O7 · 3H2O)

Habib Firouzabadi Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
,
Nasser Iranpoor Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, IranCorrespondence[email protected]
,
Hassan Hassani Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, Iran
&
Sara Sobhani Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, Iran
Pages 1967-1972 | Received 06 Jan 2004, Published online: 20 Aug 2006
 
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Abstract

Zinc dichromate trihydrate (ZnCr2O7 · 3H2O) is an efficient oxidizing agent for the immediate deprotection of 1,3‐dithianes, 1,3‐dithiolanes, and dibutyl dithioacetals to their corresponding carbonyl compounds in non‐aqueous and aprotic conditions at room temperature.

Acknowledgment

We thank Shiraz University Research Council for the partial support of this study.

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