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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 18
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Original Articles

Microwave‐Promoted Efficient Synthesis of 2‐Phosphabicyclo[2.2.2]octadiene‐ and Octene‐2‐oxides under Solvent‐Free Conditions in Diels–Alder Reaction

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Pages 3191-3199 | Received 01 Dec 2006, Published online: 10 Sep 2007

References

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  • Keglevich , Gy. 2002 . [4+2] Versus [2+2] cycloadditions in the sphere of P‐heterocycles as useful synthetic tools . Curr. Org. Chem. , 6 : 891 – 912 .
  • Keglevich , G. , Szelke , H. and Kovács , J. 2004 . Fragmentation‐related phosphinylation and phosphonylation of nucleophiles utilising the bridging P‐unit of 2‐phosphabicyclo[2.2.2]oct‐5‐ene derivatives . Curr. Org. Synth. , 1 : 377 – 389 .
  • Quin , L. D. , Tang , J.‐S. and Keglevich , G. 1991 . Diels–Alder adducts of 4‐chloro‐1,6‐dihydrophosphinine derivatives: A new precursor of 2‐phosphapropane . Heteroatom Chem. , 2 : 283 – 295 .
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  • Keglevich , G. , Újszászy , K. , Quin , L. D. and Quin , G. S. 1993 . Generation of methylene‐phosphine oxides by thermal fragmentation of derivatives of the 2‐phosphabycyclo[2.2.2]octa‐5,7‐diene oxide ring system . Heteroatom Chem. , 4 : 559 – 563 .
  • Keglevich , G. , Szelke , H. , Nagy , Z. , Dobó , A. , Novák , T. and Tőke , L. 1999 . Phosphorylation of amines by the UV light mediated fragmentation of a 2‐phosphabicyclo[2.2.2]octene 2‐oxide . J. Chem. Res. , : 580 – 581 .
  • Keglevich , G. , Szelke , H. , Dobó , A. , Nagy , Z. and Tőke , L. 2001 . Phosphorylation of phenols and naphthols by phenyl‐methylenephosphine oxide generated by the thermolysis of a 2‐phosphabicyclo[2.2.2]octa‐5,7‐diene 2‐oxide . Synth. Commun. , 31 : 1737 – 1741 .
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  • Keglevich , G. , Kovács , J. , Ludányi , K. and Tőke , L. 2002 . Novel bridged P‐heterocycles from 1,2‐dihydrophosphinine 1‐oxides . Heterocycl. Commun. , 8 : 31 – 34 .
  • Keglevich , G. , Forintos , H. and Körtvélyesi , T. 2004 . Synthesis and reactions of β‐oxophosphoranes/ylides containing a cyclic or acyclic P‐moiety . Curr. Org. Chem. , 8 : 1245 – 1261 .
  • Keglevich , G. 1993 . Synthesis of 6‐ and 7‐membered P‐heterocycles by ring enlargement . Synthesis , : 931 – 942 .

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