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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 41, 2011 - Issue 24
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Original Articles

Hydrosilylation of Ketones Catalyzed with Mg-Al-O-t-Bu Hydrotalcite

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Pages 3689-3694 | Received 12 Jul 2010, Published online: 22 Aug 2011

REFERENCES

  • Ikariya , T. ; Blacker , J. Asymmetric transfer hydrogenation of ketones with bifunctional transition-metal-based molecular catalysts . Acc. Chem. Res. 2007 , 40 , 1300 – 1308 .
  • Du , G. ; Abu-Omar , M. M. Catalytic hydrosilylation of carbonyl compounds with cationic oxorhenium(V) salen . Organometallics 2006 , 25 , 4920 – 4923 .
  • Zhu , G. ; Terry , M. ; Zhang , X. Asymmetric hydrosilylation of ketones catalyzed by ruthenium complexes with chiral tridentate ligands . J. Organomet. Chem. 1997 , 547 , 97 – 101 .
  • Moreau , C. ; Frost , C. G. ; Murrer , B. Catalytic asymmetric hydrosilylation of ketones using mixed-ligand ruthenium complexes . Tetrahedron Lett. 1999 , 40 , 5617 – 5620 .
  • Pastor , S. D. ; Shum , S. P. Novel sterically congested chiral tripodal phosphite ligands: Catalytic asymmetric hydrosilylation of ketones with a Rh(I)-TRISPHOS catalyst . Tetrahedron: Asymmetry 1998 , 9 , 543 – 546 .
  • Imamoto , T. ; Itoh , T. ; Yamanoi , Y. ; Narui , R. ; Yoshida , K. Highly enantioselective hydrosilylation of simple ketones catalyzed by rhodium complexes of P-chiral diphosphine ligands bearing tert-butylmethylphosphino groups . Tetrahedron: Asymmetry 2006 , 17 , 560 – 565 .
  • Chianese , A. R. ; Mo , A. ; Datta , D. Flexible, bowl-shaped N-heterocyclic carbene ligands: Substrate specificity in iridium-catalyzed ketone hydrosilylation . Organometallics 2009 , 28 , 465 – 472 .
  • Yun , J. ; Buchwald , S. L. Titanocene-catalyzed asymmetric ketone hydrosilylation: The effect of catalyst activation protocol and additives on the reaction rate and enantioselectivity . J. Am. Chem. Soc. 1999 , 121 , 5640 – 5644 .
  • Ushio , H. ; Mikami , K. Asymmetric reduction of ortho-multisubstituted benzophenones catalyzed by diamine-Zn-diol complexes . Tetrahedron Lett. 2005 , 46 , 2903 – 2906 .
  • Mimoun , H. ; de Saint Laumer , J. Y. ; Giannini , L. ; Scopelliti , R. ; Floriani , C. Enantioselective reduction of ketones by polymethylhydrosiloxane in the presence of chiral zinc catalysts . J. Am. Chem. Soc. 1999 , 121 , 6158 – 6166 .
  • Lipshutz , B. H. ; Lower , A. ; Noson , K. Copper(I) hydride–catalyzed asymmetric hydrosilylation of heteroaromatic ketones . Org. Lett. 2002 , 23 , 4045 – 4048 .
  • Lee , D. W. ; Yun , J. Copper-catalyzed asymmetric hydrosilylation of ketones using air- and moisture-stable precatalyst Cu(OAc)2 · H2O . Tetrahedron Lett. 2004 , 45 , 5415 – 5417 .
  • Kumbhar , P. S. ; Sanchez-Valente , J. ; Lopez , J. ; Figueras , F. Meerwein–Ponndorf–Verley reduction of carbonyl compounds catalysed by Mg–Al hydrotalcite . Chem. Commun. 1998 , 535 .
  • Choudary , B. M. ; Kantam , M. L. ; Kavita , B. ; Reddy , C. V. ; Rao , K. K. ; Figueras , F. Aldol condensations catalysed by novel Mg-Al-O-t-Bu hydrotalcite . Tetrahedron Lett. 1998 , 39 , 3555 – 3558 .
  • Choudary , B. M. ; Kantam , M. L. ; Reddy , C. V. ; Figueras , F. Catalytic C–C bond formation promoted by Mg-Al-O-t-Bu hydrotalcite . Tetrahedron 2000 , 56 , 9357 – 9364 .
  • Choudary , B. M. ; Kantam , M. L. ; Reddy , C. V. ; Aranganathan , S. ; Santhi , P. L. ; Figueras , F. Mg-Al-O-t-Bu hydrotalcite: A new and efficient heterogeneous catalyst for transesterification . J. Mol. Catal. A: Chem. 2000 , 159 , 411 – 416 .
  • Kumbhar , P. S. ; Sanchez-Valente , J. ; Figueras , F. Modified Mg–Al hydrotalcite: A highly active heterogeneous base catalyst for cyanoethylation of alcohols. Chem. Commun. 1998, 1091.
  • Choudary , B. M. ; Kantam , M. L. ; Bharathi , B. ; Reddy , C. V. Superactive Mg-Al-O-t-Bu hydrotalcite for epoxidation of olefins . Synlett 1998 , 1203 .
  • Xiang , Q. Y. ; Li , J. Y. ; Peng , J. J. ; Bai , Y. ; Hu , Y. Q. ; Lai , G. Q. Catalytic hydrosilylation of ketones using KOBu-t . Acta Chim. Sinica 2010 , 68 ( 4 ), 363 – 366 .

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