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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 45, 2015 - Issue 21
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Original Articles

Convenient In-Flow Preparation of Cr(II) Chloride for Nozaki–Hiyama–Kishi Reaction

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Pages 2473-2477 | Received 26 Jun 2015, Published online: 27 Oct 2015

REFERENCES

  • (a) Kishi, Y. Pure Appl. Chem. 1992, 64, 343–350; (b) Okude, Y.; Hirano, S.; Hiyama, T.; Nozaki, H. J. Am. Chem. Soc. 1977, 99, 3179–3181. For the reviews see (c) Fürstner, A. Chem. Rev. 1999, 99, 991–1045; (d) Wessjohann, L. A.; Scheid, G. Synthesis 1999, 1–36; (e) Fürstner, A. Chem. Eur. J. 1998, 4, 567–570; (f) Takai, K. Org. React. 2004, 64, 253–612.
  • For conceptually similar inline preparation of sensitive metallic reagent SmI2 see Voltrova, S.; Srogl, J. Synlett 2013, 24, 0394–0396.
  • Typically the reagent is prepared using Schlenk technique and its quality varies depending on what remaining components are present in the resulting solution. For further details see the review in Ref. 1(c).
  • (a) Roe, M. B.; Whittaker, M.; Procter, G. Tetrahedron Lett. 1995, 36, 8103–8106; (b) Oddon, G.; Uguen, D. Tetrahedron Lett. 1998, 39, 1157–1160.
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  • Cervinka, O.; Suchan, V.; Masar, B. Collect. Czech. Chem. Commun. 1965, 30, 1693–1699.
  • Krasovskiy, A.; Knochel, P. Angew. Chem. Int. Ed. 2004, 43, 3333–3336.
  • Mahmoodi, N. O.; Salehpour, M. J. Heterocycl. Chem. 2003, 40, 875–878.
  • Al-Hamdany, R.; Al-Rawi, J. M.; Ibrahim, S. J. Prakt. Chem. 1987, 329, 126–130.

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