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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 8, 1978 - Issue 2
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Original Articles

Reinvestigation of the Reaction of Caro's Acid with 3-Aminopyrideine. An Improved Synthesis and Characterization of 3,3′-Azoxypyridine

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Pages 109-115 | Received 20 Nov 1977, Published online: 05 Dec 2006

References

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  • Sulfomonoperacid
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  • Kimura , M. and Takano , Y. 1959 . Yakugaku Zasshi , 79 : 549 Chem. Abstr., 53, 18030d (1959)
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  • When 3-aminopyridine (Reilly Tar and Chemical Co.) was used without sublimation, the initial acid solution of the heterocycle was deep purple. The yields were not affected by the purity of the 3-aminopyridine
  • Loev , B. and Goodman , M. M. 1967 . Chem. Ind. , : 2026 If dry column chromatography was not performed, the 3,3′-azoxypyridine was yellow-orange needles after two recrystallizations, m. p. 127–128°C
  • The following numbering system was used during the analysis of both the proton and carbon NMR spectra:

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