References
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- Forman , L. and Sears , W. C. 1954 . J. Am. Chem. Soc. , 76 : 4977 These workers observed de-t-butylation in the reaction of 3-methyl-4,6-di-t-butylphenol with excess bromine or chlorine
- Kalibabchuk , N. N. and Pokhodenko , V. D. 1968 . J. Org. Chem. USSR , 4 : 320
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- Cyclic phosphate esters such as ethylene phosphate may react faster than TMP with HX.13
- Westheimer , F. H. 1968 . Acc. Chem. Res. , 1 : 70
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- Caló , V. , Lopez , L. and Valentino , D. S. 1978 . Synthesis. , : 139 These authors employed cyclohexene epoxide as a scavenger for HBr in the free - radical bromination of ketones
- Preliminary experiments have indicated that TMP may not be as useful in the halogenation of amines. For instance, aniline was brominated to a mixture of p-bromoaniline (5%), 2,4,6-tribromoaniline (1%), and an unidentified water soluble compound. However, dimethylaniline gave p-bromodimethylaniline in 71% yield