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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 13, 1983 - Issue 14
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Original Articles

A Silicon Mediated Conversion of Esters to Terminal Olefins and Specifically Deuterated Olefins

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Pages 1163-1167 | Published online: 05 Dec 2006

References

  • The chemistry of α-silyl carbonyl compounds part 5
  • de , V. C. and UPR , M. 1983 . Graduate student supported by the NIH-MBRS (RR-8102-10) program Taken in part from the M. Sc. thesis of
  • Barluenga , J. , Yus , M. , Concellón , J. M. and Bernad , P. 1983 . J. Org. Chem. , 48 : 609 – 611 . references therein
  • Larson , G. L. and Fuentes , L. M. 1981 . J. Am. Chem. Soc. , 103 : 2418 – 2419 .
  • Honda , S. and Hata , T. 1981 . Tetrahedron Lett. , 22 : 2093 – 2096 . The LAH reduction of ethyl (diphenylmethylsilyl)acetate has been reported
  • Deuteration was carried out with a solution of the ester in DMSO-d6 with a catalytic amount of KH over 48 h
  • Larson , G. L. and Hernández , D. 1982 . Tetrahedron Lett. , 23 : 1035 – 1038 .

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