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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 16, 1986 - Issue 3
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Original Articles

New Synthesis of 1,1,1-Tricarboalkoxy Derivatives: Masked 1,1-Diesters

Pages 291-298 | Published online: 19 Dec 2006

References

  • Boehme , H. and Haefner , L. 1966 . Chem. Ber. , 99 : 281
  • Prelicz , D. , Witek , H. and Wyzgowska , L. 1967 . Rocz. Chem. , 41 : 267
  • Padgett , H. C. , Csendes , I. G. and Rapoport , H. 1979 . J. Org. Chem. , 44 : 3492
  • Decarbalkoxylation also occurs on contact with (aq) basic solutions.
  • Isolated yields from chromatography HRMS values are (exp): 1- m/e = 287. 1502; 2- m/e = 287.1491 (m/e (calcd) = 287.1494), 3- m/e = 315.1805, m/e (calcd) = 315.1807.
  • Krapcho , A. P. , Glynn , G. A. and Grenon , B. J. 1967 . Tetrahedron Lett. , 8 : 215 Decarbalkoxylation of gem-diethyl esters
  • No reaction has occurred in the absence of KCN after 18 h.
  • Corey , E. G. and Suggs , J. W . 1975 . Tetrahedron Lett. , 2647
  • Levine , S. G. 1958 . J. Am. Chem. Soc. , 80 : 6150
  • Deslongchamps , P. , Lamothe , S. and Lin , H. S. 1984 . Can. J. Chem. , 62 : 2395

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