Preparation of Aromatic Fluorides Via Diazotization and Photochemically Induced Fluoro-Dediazoniation of Aromatic Amines in Anhydrous Hydrogen Fluoride - Organic Base Solutions

References

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• Clear evidence for the formation of Ar+ from ArN2 + by irradiation has not been obtained yet in our experiments. One electron transfer mechanism in the formation of Ar+ from initialy formed Ar by irradiation might be an adequate explanation for our reactions. We are grateful to Prof. T. Sonoda (Kyushu Univ.) for his helpful discussions.
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• Yoneda , N. and Fukuhara , T. Unpublished results. The scope and limitation of the photochemically induced fluoro-dedizoniation of various Ar-N2X salts using AHF-base solutions or other solvents are under investigation.
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