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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 9-10
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Original Articles

Enantioconvergent Synthesis of (-)-α-Cuparenone Involving Chiral Inversion of a Ketone Intermediate

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Pages 1813-1823 | Received 07 Dec 1988, Published online: 24 Oct 2006

References

  • 1988 . National Symposium on Organic Synthesis , Nandesari, Vadodara, , India : Malti-Chem. Research Centre . NCL Communication No. 4566. This work was presented at the held on November 1 and 2, at 391340
  • Meyers , A. I. and Lefker , B. A. 1986 . J. Org. Chem. , 51 : 1541 and references cited therein.
  • Greene , A. E. , Charbonnier , F. , Luche , M. J. and Moyano , A. 1987 . J. Am. Chem. Soc. , 109 : 4752 and referenced cited therein.
  • Though we have discussed about effecting chiral inversion through 1,2-ketone transposition of odd membered carbocycles, effecting chiral inversion is not limited to such cases; chiral inversion can also be carried out with unsaturated ketones; for example chiral inversion of (-)-carvone has already been reported by us6
  • Gharpure , M. M. and Rao , A. S. in press . Synthetic Commun. ,
  • Honwad , V. K. , Siscovic , E. and Rao , A. S. 1967 . Indian J. Chem. , 5 : 234

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