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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 2
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Original Articles

A Practical Approach to Homo Trialkyl Phosphonates: A Catalytic Michaelis-Arbuzov Reaction

Pages 239-246 | Received 11 Sep 1989, Published online: 24 Oct 2006

References

  • Trialkyl phosphites and phosphonates with all the three alkyl groups the same are herein referred to as ‘homo’ trialkyl phosphites and phosphonates, respectively. These with at least one alkyl group different from the remaining two are referred to as the corresponding ‘pseudo’ derivatives
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  • Chemical Abstracts up until mid 1989, bear no information on iodine catalyzed phosphite‐phosphonate isomerization! 20. Within the detection limits of 13C and 1H NMR (Varian XL‐300), there were no foreign signals noted and thus the purity of the phosphonates prepared in this study is better than 95%

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