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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 20, 1990 - Issue 4
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Original Articles

A Convenient Synthesis of Tertiary Isothiocyanates and Acyl Isothiocyanates Using Phosphoryl Isothiocyanate

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Pages 509-513 | Received 04 Oct 1989, Published online: 24 Oct 2006

References

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  • Refluxing a mixture of POCl3 (0.05 mol), KSCN (0.2 mol), 18‐crown‐6 (0.005 mol) and benzene (50 ml) for 6 h afforded PO(NCS)3 (0.04 mol, 80%), b.p. 120–122°C/1.2 mmHg. The yield was not optimized

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