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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 8-9
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Original Articles

A Convenient Method for the Conversion of α-Tetralones to Aryl Acetates

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Pages 989-996 | Received 19 Feb 1991, Published online: 23 Sep 2006

References

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  • 1b: IR (KBr) 2992,2934, 2833, 1757, 1647, 1600, 1505, 1483, 1369, 1325, 1289, 1264, 1211, 1094, 1034; 1H NMR (CDCl3) δ 2.35 (s, 3 H), 3.29 (s, 3 H), 3.96 (s, 3 H), 3.97 (s, 3 H), 4.70 (d, J = 16 Hz, 1H), 6.02 (AB, J = 1.5 Hz, 2 H), 6.27 (d, J = 2.5 Hz, 1 H), 6.78 (d, J = 6.5 Hz, 1 H), 7.08 (s, 1 H), 7.73 (s, 1 H). HRMS calcd. for C23H21NO7: 424.1396; found: 424.1388. 3b: IR (neat) 3061, 1756, 1659, 1369, 1338, 1209, 1126, 1076, 1038, 917, 768; 1H NMR (CDCl3) δ 2.30 (s, 3 H), 2.42–2.50 (m, 2 H), 2.87 (t, J = 8 Hz, 2 H), 5.71 (t, J = 5 Hz, 1 H), 7.08–7.20 (m, 2 H). HRMS calcd. for C12H13O2: 189.0916; found: 189.0912. 5b: IR (neat) 2935, 2885, 1763, 1659, 1606, 1476, 1439, 1369, 1215, 1164, 1120, 1012; 1H NMr (CDCl3) δ 2.24 (s, 3 H), 2.27 (s, 3 H), 2.30 (s, 3 H), 2.40–2.45 (m, 2 H), 2.77 (t, J = 8.0 Hz, 2 H), 5.66 (t, J = 5.0 Hz, 1 H), 6.77 (s, 1 H), 6.89 (s, 1 H). HRMS calcd. for C14H17O2: 217.1229; found: 217.1222
  • Cushman , M. and Cheng , L. 1978 . J. Org. Chem. , 43 : 286
  • Ishii , H. , Chen , I. S. and Ishikawa , T. 1987 . J. Chem. Soc. Perkin Trans. I , : 671
  • Saldtler Standard N.M.R. Spectra, Vol. 26, 17313M; Sadtler Standard Infrared Prism Spectra, Vol. 44, 44969
  • Sadtler Standard N.M.R. Spectra, Vol. 74, 41929M; Sadtler Standard Infrared Prism Spectra, Vol. 80, 69032

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