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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 5
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Original Articles

MnO2/Bentonite: A New Reactive for the Oxidation of Hantzsch'S Dihydropyridines Using Microwave Irradiation, in the Absence of Solvent (I)

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Pages 619-624 | Received 04 Jan 1991, Published online: 23 Sep 2006

References

  • Gedye , R. , Smith , F. , Westaway , K. , Ali , H. , Labergue , L. and Rousell , J. 1986 . Tetrahedron Lett. , 27 : 79
  • Giguere , R. J. , Bray , T. L. , Duncan , S. M. and Majetich , G. 1986 . Tetrahedron Let. , 27 : 4945
  • Gedye , R. N. , Smith , F. E. and Westaway , K. C. 1988 . Can. J. Chem. , 66 : 17
  • Bram , G. and Loupy , A. 1987 . “Preparative Chemistry using Supported Reagents” , Edited by: Laszlo , P. San Diego : Academic Press .
  • Gutierrez , E. , Loupy , A. , Bram , G. and Ruiz-Hitzky , E. 1989 . Tetrahedron Lett. , 30 : 945
  • Bram , G. , Loupy , A. and Majdous , M. 1990 . Synthetic Commun. , 20 : 125
  • Hantzsch , A. 1882 . Ann. , 215 : 1
  • 1,4-dihydropyridines in boiling hexane or benzene were not oxidized with MnO2/Bentonite system
  • MnO2/Bentonite A was prepared using 1:2 ratio of KMnO4 and Mexican Bentonite in acetone, until discharge the purple color of the solution, filtered and the solid brown activated for 24 h. at 120°C. MnO2/Bentonite B was prepared in the same form, but using a relation KMnO4 and Mexican Bentonite 1:4
  • Loev , B. and Snader , K. 1965 . J. Org. Chem. , 30 : 1914
  • Kamal , A. , Ahmad , M. , Mohd , N. and Hamid , A. 1969 . Bull. Soc. Chem. Jap. , 37 : 610
  • Alvarez , C. , Cano , A. C. , Rivera , V. and Márquez , C. 1987 . Synthetic Commun. , 17 : 279 The Mexican Bentonite was used for to regenerate carbonyl compounds from their corresponding oximes and semicar-bazones
  • Cano , A. C. , Delgado , F. , Códoba , A. A. , Márquez , C. and Alvarez , C. 1988 . Synthetic Commun. , 18 : 2051
  • Interesting results were observed in the oxidation of 4-alkyl-1,4-dihydropyridines with MnO2/Bentonite, following communication in this journal

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