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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 16
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Original Articles

Cobalt(II) Complex Catalysed Epoxidation with Molecular Oxygen

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Pages 2285-2292 | Received 23 Mar 1993, Published online: 23 Sep 2006

References

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  • Complex 1 is prepared by mixing ephedrine (A) (10 mmol) and dry CoCl2 (5 mmol) in dry acetonitrile under nitrogen at ambient temperature. Satisfactory spectroscopic and elemental analyses were obtained for this complex.
  • Complex 2 is prepared by mixing ligand (B) (prepared accordingly to ref. 3c) and Cocl2 in acetonitrile at room temperature and it was crystallised from acetonitrile, to give satisfactory elemental analysis.
  • Richard , E. L. , Abiko , A. and Masamune , S. 1990 . Tet. Lett. , 31 : 6005

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