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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 10
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Original Articles

Diels-Alder Reactions of 1,3-Cyclohexadienes and 3-(Trimethylsilyl)propynoates. A New Synthesis of Ortho-(Trimethylsilyl)benzoate Esters.

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Pages 1793-1799 | Received 03 Dec 1996, Published online: 22 Aug 2006

REFERENCES AND NOTES

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  • I-Methoxy-1,3-cyclohexadiene is available from Aldrich Chemical Co., Inc. as a 65:35 mixture of 1-methoxy-1,3-cyclohexadiene and 1-methoxy-1,4-cyclohexadiene. A small amount (9% yield) of an inseparable 1:1 mixture of 6 and 7 was also isolated from the reaction mixture. Compounds 6 and 7 presumably arise from reaction of 2-methoxy-1,3-cyclohexadiene formed by isomerization of 1-methoxy-1,4-cyclohexadiene under the reaction conditions.

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