30
Views
3
CrossRef citations to date
0
Altmetric
Articles

Ruthenium(III) mediated oxidation of glycerol by cerium(IV) in aqueous sulfuric acid medium – a kinetic and mechanistic study

, , &
Pages 283-298 | Received 04 Jul 2009, Accepted 20 Sep 2009, Published online: 24 Nov 2009

References

  • Marshal , A. T. and Haver Kamp , R. G. 2008 . Production of Hydrogen by the Electrochemical Reforming of Glycerol–Water Solution in a PEM Electrolysis Cell . Int. J. Hydro. Energ , 33 : 4649
  • Patil , R. K. , Chimatadar , S. A. and Nandibewoor , S. T. 2008 . Mechanistic Study of Cerium(IV) Oxidation of Antimony (III) in Aqueous Sulphuric Acid in the Presence of Microamounts of Manganese(II) by Stopped Flow Technique . Transition Met. Chem , 33 : 625
  • Day , M. C. and Selbin , J. 1964 . Theoretical Inorganic Chemistry , 226 New York : Reinhold Publishing Corporation .
  • Yatsimirskii , K. B. and Luzan , A. A. 1965 . Mechanism and Kinetics for the Cerium Oxalate Reaction . Zh. Neorg. Khim , 10 : 2268
  • Caroll , R. L. and Thomas , L. B. 1966 . The Kinetic and Mechanism of the Oxidation of Hypophosphrous Acid by Cerium(IV) in Aqueous Perchloric Acid Solution . J. Am. Chem. Soc , 88 : 1376
  • Madhav , B. R. , Sastry , T. P. and Parekhi , T. S. 1983 . A Comparative Kinetic Study of Oxidation Structurally Related Organic Substrate viz. Succinic, Malic and Tartaric Acids and also of Glycerol with Cerium(IV) Sulphate in Sulphuric Acid Medium . Z. Phys. Chem. i.e. Leipzig , 5 : 264
  • Desai , S. M. , Halligudi , N. N. and Nandibewoor , S. T. 2002 . Kinetics and Mechanism of Ruthenium(III) Catalysed Oxidation of Allyl Alcohol by Acid Bromate Autocatalysis in Catalysis . Transtion Met. Chem , 27 : 207
  • Hiremath , G. A. , Timmanagoudar , P. L. and Nandibewoor , S. T. 1998 . Ruthenium(III) Catalysed Oxidation Hexacynoferrate(II) by Periodate in Aqueous Alkaline Medium . React. Kineti. Catal. Lett , 63 : 403
  • Latimer , W. M. 1959 . Oxidation Potentials , 2nd ed , 343 New Jersey : Prentice- Hall .
  • Jeffery , G. H. , Bassett , J. , Mendham , J. and Denney , R. C. 1996 . Vogel's textbook of quantitative chemical analysis , 5th ed , 329 Essex, , England : ELBS, Longman .
  • Radhakrishnamurti , P. S. and Panda , H. D. 2004 . Titanium(III) Oxidation of Alkenes and Alkynes and Ruthenium(III) Catalysis in the Oxidation of Alkenes: a Kinetic and Mechanistic Study . Int. J. Chem. Kinet , 15 : 587
  • Kamble , D. L. , Chougle , R. B. and Nandibewoor , S. T. 1996 . Kinetic and Mechanism of Uncatalysed and Ruthenium(III) Catalysed Oxidation of Allay Alcohol by N- Bromosuccinamide in Aqueous Alkaline Medium . Indian J. Chem. A , 35 : 865
  • Fiegl , F. 1975 . Spot Test in Organic Analysis , 435 New York : Elsevier .
  • Kulba , F. Ya. , Yakovlev , Yu B. and V. E. 1965 . Mironov, Potentiometric Study of Sulphatocomplexes of Thallium . Russ. J. Inorg. Chem , 10 : 1113
  • Kharzeoua , S. E. and Serebrennikou , V. V. 1967 . Study of Sulphato Complexes of Cerium(IV) by Infrared Absoption Spectra . Russ. J. Inorg. Chem , 12 : 1601
  • Moelwyn-Hughes , E. A. 1947 . Kinetics of Reaction in Solutions , 297 London : Oxford University Press .
  • Daugherty , N. A. and Taylor , R. L. 1972 . The Kinetics of the Cerium(IV) Reaction in Perchloric Acid . J. Inorg. Nucl. Chem , 34 : 1756
  • Krishna , B. K. and Tiwari , K. C. 1961 . Kinetic and Mechanism of Oxidation of Mandelic, dl-Malic and Lactic Acid by Ceric Sulphate . J. Chem. Soc , : 3097
  • Senguupta , K. K. 1965 . Kinetics of the Oxidation of Malic Acid by Cerium(IV) . J. Indian Chem. Soc , 42 : 725
  • Mehrotra , R. N. and Ghosh , S. 1966 . Kinetic Study of the Oxidation of Fructose by Ceric Sulphate in Aqueous Sulphuric Acid Medium . Z. Phys. Chem , 231 : 91
  • Chimatadar , S. A. , Madawale , S. V. and Nandibewoor , S. T. 2007 . Mechanistic Study of Iodide Catalysed Oxidation of l-Glutanic Acid by Cerium (IV) in Aqueous Sulphuric Acid Medium . Transition Met. Chem , 32 : 634
  • Kamble , D. L. and Nandibewoor , S. T. 1998 . Osmium (VIII)/ Ruthenium (III) Catalysis of Periodate Oxidation of Acetaldehyde in Aqueous Alkaline Medium . J. Phys. Org. Chem , 11 : 171
  • Hiremath , D. C. , Kiran , T. S. and Nandibewoor , S. T. 2007 . Oxidation of Vanillin by Diperiodatocuprate (III) in Aqueous Alkaline Medium – A Kinetic and Mechanistic Study (Stopped Flow Technique) . Int. J. Chem. Kinet , 39 : 1
  • Walling , C. 1957 . Free Radicals, in Solutions , 38 New York : Academic Press .
  • Farokhi , S. A. , Nandibewoor , S. T. and Kinetic . 2003 . Mechanistic and Spectral Studies for the Oxidation of Sulfanilic Acid by Alkaline Hexacynoferrate . Tetrahedron , 59 : 7595

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.