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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 19
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Original Articles

THE BAYLIS—HILLMAN REACTION: TiCl4 MEDIATED COUPLING OF ALKYL VINYL KETONES WITH α-KETO ESTERS AND ALDEHYDES

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Pages 2987-2995 | Received 22 Sep 2000, Published online: 16 Aug 2006

REFERENCES

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  • Work up by addition of water provided allyl chloride as major product. However addition of conc. HCl gives better results. Our attempts to obtain the Baylis–Hillman alcohol i.e. 4-hydroxy-3-methylene-4-phenylbutan-2-one in this reaction were not successful
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