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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 21
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Original Articles

Total Synthesis of (±)‐Infuscol A and (±)‐Cuprenenol

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Pages 3847-3864 | Received 14 Jun 2004, Published online: 10 Jan 2011

References

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  • Nagashima , F. , Suzuki , M. , Takaoka , S. and Asakawa , Y. 2001 . Sesqui‐ and diterpenoids from the Japanese liverwort Jungermannia infusca . J. Nat. Prod. , 64 : 1309 – 1317 . [PUBMED] [INFOTRIEVE] [CSA]
  • Matsuo , A. , Terada , I. , Nakayama , M. and Hayashi , S. 1977 . Cuprenenol and rosulantol, new cuparane class sesquiterpene alcohols from the liverwort Jungermannia rosulans . Tetrahedron Lett. , : 3821 – 3824 . For the first report on the isolation of cuprenenol from Jungermannia Rosulans, see:[CROSSREF]
  • Nagashima , F. , Tanaka , H. , Takaoka , S. and Asakawa , Y. 1997 . Sesqui‐ and diterpenoids from the Japanese liverwort Jungermannia hattoriana . Phytochemistry , 45 : 353 – 363 . For the isolation of cuprenenol and neocuprenenols from Jungermannia infusca collected at different locations, see:[CROSSREF]
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  • To the best of our knowledge, there is no report in the literature on the synthesis of these nonaromatic cuparenoids infuscols A‐D, cuprenenol, and neocuprenenol
  • Johnson , W. S. , Werthemann , L. , Bartlett , W. R. , Brocksom , T. J. , Li , T.‐t. , Faulkner , D. J. and Petersen , M. R. 1970 . A simple stereoselective version of the Claisen rearrangement leading to trans trisubstituted olefinic bonds. Synthesis of squalene . J. Am. Chem. Soc. , 92 : 741 – 743 .
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  • Srikrishna , A. , Reddy , T. J. , Kumar , P. P. and Vijaykumar , D. 1996 . A methodology for spirocyclopentannulation. Stereoselective total synthesis of tochuinyl acetate and dihydrotochuinyl acetate . Synlett , : 67 – 68 . [CROSSREF]
  • Grieco , P. A. , Nishizawa , M. , Marinovic , N. and Ehmann , W. J. 1976 . Remote double bond migration via rhodium catalysis: A novel enone transposition . J. Am. Chem. Soc. , 98 : 7102 – 7104 .

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