Advanced search
Publication Cover
Free Radical Research Communications Volume 19, 1993 - Issue sup1: Third International Symposium on Spin Trapping and Aminoxyl Radical Chemistry
Journal homepage
16
Views
20
CrossRef citations to date
0
Altmetric
Original Article

β-Phosphorylated Five Membered Ring Nitroxides. Synthesis and EPR Study

L. Dembkowski Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
,
J. P. Finet Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
,
C. Fréjaville Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
,
F. Le Moigne Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
,
R. Maurin Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
,
A. Mercier Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
,
P. Pages Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
,
P. Stipa Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
&
P. Tordo Université de Provence, CNRS URA 1412, Radicaux Libres et Synthèse, case 521, Av. Escadrille Normandie-Niemen, 13397 Marseille Cedex 13, France
 show all
Pages s23-s32 | Published online: 07 Jun 2011

References

  • (a) CF. Chignell (1984) Use of spin-labels as enzyme probes. In Spin-Labelling in Pharmacology {tá, J.L. Holt/man). Academic Press, pp. 131–156. (b) E.J. Rauckrnan, G.M. Rosen and L.K. Griffeih (1984) En/.ymalic reactions of spin-labels, ibid, pp. 175–189. (c) L.J. Berliner (1976, 1979) Spin labelling. Theory and Applications, I and II. Academic Press, New York. (d)0. Sosnovsky, N.lJ.M. Rao. S.W. l.i and H.M. Swariz (1989) Synthesis of niiroxyl (aminoxyl) labeled probes for studies of intracellular environment by EPRand MRL Journal of Organic Chemistry, 54, 54–3667. (e) J.F.W. Keana (1984) Spin-labelling in Pharmacology (ed. J.L. Holtzman) Academic Press, London and New York, pp. 2–67. (0 E.G. Janzcn and R.A. Towner (1992), Aminoxyl Radicals as MRI Contrast Agents, in Bioactive Spin Labels (Ed. R.l. Zhdanov), Springet-Vcrlag, Heidelberg, pp. 573–583.
  • J.F.W. Keana. L. Lex. J.S. Mann, J.M. May, J.H. Park. S. Pou. V.S. Prabhu. G.M. Rosen. BJ. Sweetman and Y. Wu (1990) Novel nitroxides Tor spin-labelling, -trapping, and magnetic resonance imaging applications. Pure and Applied Chemistry, 62, 201–205.
  • (a) M.J. Perkins (1980) Spin Trapping. In Advances in Physical Organic Chemislry (Ed. V. Gold and D. Bethell), Academic Press, London, pp. 1–64. (b) E.G. Janzen (1980) A critical review of spin trapping in biological systems. In Free Radicals in Biology (Ed, W.A. Pryor), Academic Press. New York, pp. 115–154. (c) G.M. Rosen and E. Finkelsicin (1985) Use of Spin Traps in Biological Systems. Advances in Free Radical Biology and Medicine, 1, 345–375.
  • J.F.W. Keana, F.L. Van Nice (1984) Influence of structure on the reduction of nitroxidc MRI contrast-enhancing agents by ascorbaie. Physiological Chemistry and Physics and Medical NMR, 16, 477–480.
  • D.F. Bowman. T. Gillan and K.U. Ingold (1971) Kinetic applications of election paramagnetic resonance spectroscopy. IN. Self reactions of dialkyl nitroxidc radicals. Journal of the American Chemical Society, 93, 6555 6561.
  • Muller-Warmuth W. and Meise-Gresh K. (1983) Molecular motions and interactions as studied by dynamic nuclear polarization (DNP) in free radical solutions. Advances ili Mannelli-Resonance (Ed. J.S. Waught), Academic Press, (b) Y. Ayani. R. Bcsson, R. Casalagno (1980) Interprétation théorique de la forme des raies obtenues par polarisation dynamique dans les solutions de radicaux libres, Journal de Physique, 4, 1183–1192. (c) Y. Ayant and R. Casalegno (1978) Effet du mode de relaxation sur le coefficient de polarisation dynamique dans les solutions de radicaux libres. Journal de Physique, 39. 39–235. (d) R.H. Poindcxtcr. J.R. Stewart and P.J. Captan (1967) Dynamic polarization of fluorine nuclei in solutions of selected Tree radicals, Journal of Chemical Physics, 47. 47–2862. (c) Y. Bcrchadsky, N. Kernevez, F. Le Moigne, A. Mercier. L. Sccuurgeon. P. Tordo (1990). Preparation of heterocyclic phosphono nitroxides, firit-UK Pat. Appi- GB 2, 225, 015 {Chemical Abstracts, 113. I9l636w). (f)Y. Ayant, N. Kernevez, L. Sccourgeoti, P. Tordo (I990) Weak Field Dynamic Nuclear Polarization with Phosphorus Radicals in Congress Ampere on Magnetic Resonance and Related Phenomena, Ed. M. Mchring, J.U. Von Schutz, H.C. and Wolf. Spfinger-Vcrlag. 188–189.
  • A. Mercier, Y. Bcrchadsky, Badrudin.S. Pietri and P, Tordo (1991)3-phosphorylatcd fivemembered ring nitroxides. a new class of stable nitroxides. 1. Synthesis by reaction of dialkylphosphites with 1-pyrroIine-N-oxides Tetrahedron Letters. 32. 2125–2128.
  • F. l-e Moigne, A. Mercier and P. Tordo (1991) tf-phosphor)1 lai ed cyclic nitroxides. 2. Synthesis of pyrrolidin- and pÌperÌdin-2-yl phosphonates and the corresponding Mablc nitroxides. Tetrahedron Letters, 32, 3841–3844.
  • E.G. Janzen (1984) Electron spin resonance study of the hyperfine splitting constants of naturally abundant carbon-13 and nitrogen-15 in diphcnylmelhyl r-hutyl aininoxyl (nitroxide). Solvent and temperature effects, Conadian Journal of Chemistry, 62. 1653–1657.
  • F. Vila, G. Pepe. D. Siri and P. Tordo Force field calculations on five membercd ring aminoxyl radicals, Free Radical Research Communications, in press.
  • P. Tordo, M. Boyer, A. Friedmann. O. Santero, and L. Pujol (1978) Phosphorus-substituted nitroxides. 3. Hypereonjugative ability of carbon-phosphorus bonds in five-membered-ring nitroxides. Journal of physical chemistry, 82, 1742–1744.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.