158
Views
140
CrossRef citations to date
0
Altmetric
Original Article

Reaction of Ferrate (VI)/Ferrate (V) with Hydrogen Peroxide and Superoxide Anion - a Stopped-Flow and Premix Pulse Radiolysis Study

, &
Pages 187-198 | Received 05 Jul 1995, Published online: 07 Jul 2009

References

  • Audette R. J., Quail J. W., Smith P. J. Oxidation of substituted benzyl alcohols with Ferrate(V1) ion. Journal of the Chemical Society. Chemical Communications 1972; 38–39
  • Groves J. T., McClusky G. A. Aliphatic hydroxylation via oxygen rebound. Oxygen tranfer catalyzed by iron. The Journal of the American Chemical Society 1976; 98: 859–861
  • Carr J. D., Kelter P. B., Tabatabai A., Spichal D., Erickson J., McLaughlin C. W. Properties of ferrate(VI) in aqueous solution: an alternate oxidant in wastewater treatment. Water Chlorination: Chemistry, Environmental Impact and Health Effects. Proc. 5th Conf. Water Chlorination: Environmental Impact and Health Effects, Chelsea, Michigan, 1985, R. L. Jolley, R. J. Bull, W. P. Davis, S. Katz, M. H. Roberts, Jr, V. A. Jacobs. Lewis Publishers, Inc., 5: 1285–1298
  • Barzatt R., Carr J. The kinetics of oxidation of low molecular weight aldehydes by potassium ferrate. Transition Metal Chemistry 1986; 11: 414–416
  • Hoppe M. L., Schlemper E. L., Murmann R. K. Structure of dipotassium ferrate(VI). Acta Crystallographica, Section B 1982; 38: 2237–2239
  • Heber R. H., Johnson D. Lattice Dynamics and Hyperfine Interactions in M2FeO4 (M = Kf, Rb+, Cs+) and M'FeO4 (M' = Sr2+, Ba2+). Inorganic Chemistry 1979; 18: 2786–2790
  • Carrington C., Schonland D., Symons M. C.R. Structure and Reactivity of the Oxyanions of Transition Metals. Part IV. Some Reactions between Electronic Spectra and Structure. The Journal of the Chemical Society 1957; 659–666
  • Wood R. H. The Heat, Free Energy and Entropy of the Ferrate(V1) Ion. The Journal of the American Chemical Society 1958; 80: 2038–2041
  • Goff H., Murmann R. K. Studies of the Mechanism of Isotopic Oxygen Exchange and Reduction of Ferrate(VI) Ion (FeO42–). The Journal of the American Chemical Society 1971; 93: 6058–6065
  • Williams D. H., Riley J. T. Preparation and alcohol oxidation studies of the Ferrate(VI) ion, FeO42–. Inorganica Chimica Acta 1974; 8: 177–183
  • Cyr J. E., Bielski B. H.J. The Reduction of Ferrate(VI) to Ferrate(V) by Ascorbate. Free Radical Biology & Medicine 1991; 11: 157–160
  • Shanna V. K., Bielski B. H.J. Reactivity of Ferrate(VI) and Ferrate(V) with Amino Acids. Inorganic Chemistry 1991; 30: 4306–4310
  • Bielski B. H.J., Sharma V. K., Czapski G. Reactivity of Ferrate(V) with Carboxylic Acids. A Pre-Mix Pulse Radiolysis Study. Radiation Physics and Chemistry 1994; 44: 479–484
  • Rush J. D., Cyr J. E., Bielski B. H.J. The Oxidation of Phenol by Ferrate(VI) and Ferrate(V). A Pulse Radiolysis and Stopped-Flow Study. Free Radical Research Communications 1995; 22: 349–360
  • Bielski B. H.J., Rush J. D. The Oxidation of Amino Acids by Ferrate(V). A Pre-Mix Pulse Radiolysis Study. Free Radical Research Communications 1995; 22: 571–579
  • Rush J. D., Bielski B. H.J. Pulse Radiolysis Studies of Alkaline Fe(III) and Fe(VI) Solutions. Observations of Tranient Iron Complexes with Intermediate Oxidation States. The Journal of the American Chemical Society 1986; 108: 523–525
  • Bielski B. H.J., Thomas M. J. Studies of Hypervalent Iron in Aqueous Solutions. Radiation Induced Reduction of Iron(VI) to Iron(V) by CO2–. The Journal of the American Chemical Society 1987; 109: 7761–7764
  • Rush J. D., Bielski B. H.J. Kinetics of Ferrate(V) Decay in Aqueous Solution. A Pulse Radiolysis Study. Inorganic Chemistry 1989; 28: 3947–3951
  • Thompson G. W., Ockerman L. T., Schreyer J. M. Preparation and purification of potassium ferrate (VI). The Journal of the American Chemical Society 1951; 73: 1379–1381
  • Zhongwei Zhao, Rush J. D., Holcman J, Bielski B. H.J. The aidation of ChromiumfIII) by Hydroxyl Radical in Alkaline Solution. A Stopped-Flow and Pre-Mix Pulse Radiolysis Study. Radiation Physic and Chemistry 1995; 45: 257–263
  • Birus M., Kujundzic N., Pribanic M. Kineti of Complexation of Iron(III) in Aqueous Solution. In. Progress in Reaction Kinetics 1993; 18: 171–271
  • Conocchioli T. J., Hamilton E. J., Jr., Sutin N. The formahon of Iron(IV) in the Oxidation of Lron(II). The Journal of the American Chemical Society 1965; 87: 926–927
  • Schwarz H. A. Free radicals generated by radiolysis of aqueous solutions. Journal of Chemical Education 1981; 58: 101–105
  • Bwton G. V., Greenstock C. L., Hellman W. P., Ross A. B. Critical Review of Rate Constants for Reactions of Hydrated Electron, Hydrogen Atoms and Hydroxyl Radicals (OH/O−) in Aqueous Solution. The Journal of Physical Chemistry and Chemical Reference Data 1988; 17: 513–886
  • Neta P., Huie R. E., Ross A. B. Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution. Journal of Physical and Chemical Reference Data 1988; 17: 1027–1284
  • Bielski B. H.J., Cabelli D. E., Arudi R. L., Rass A. B. Reactivity of HO2/O2−− Radicals in Aqueous Solution. Journal of Physical and Chemical Reference Data 1985; 14: 1041–1100
  • Ernst T., Wawrzenska M., Cyfert M., Wronska M. Effect of pH on the kinetics of ferrate(VI) decomposition. Bull. Acad. Polon. Sci 1979; 10: 773–778
  • Stuglik Z., Zagorski Z. Pulse Radiolysis of Neutral Iron(II) Solutions: Oxidation of Ferrous Ions by OH Radicals. Radiation Physics and Chemistry 1981; 17: 229–233
  • Rush J. D., Bielski B. H.J. Pulse Radiolytic Studies of the Reactions of HO2/O2−− with Ferric Ions and its Implication on the Occurence of the Haber-Weiss Reaction. Journal of Physical Chemistry 1985; 89: 5062–5066
  • Rush J. D., Bielski B. H.J. The Decay of Ferrate(V) in Neutral and Acidic Solutions. A Pre-Mix Pulse Radiolysis Study. Inorganic Chemistry 1994; 33: 5499–5502
  • Melton J. D., Bielski B. H.J. Studies of the Kinetics, Spectral and Chemical Properties of Fe(VI) Pyrophosphate by Pulse Radiolysis. Radiation Physics and Chemistry 1990; 36: 725–733
  • Smith R. M., Martell A. E. Critical Stability Constants. Inorganic Complexes. Plenum Press, New York 1976; 4
  • Swineheart J. H., Castellan W. The Kinetics of the Chromate-Dichromate Reaction as Studied by a Relaxation Method. Inorganic Chemistry 1964; 3: 278–280
  • Cotton F. A., WdkLnson G. Advanced Inorganic Chemistry. 3rd ed. Intersaence Publishers, New York 1962; 854
  • J.D. Rush and B.H.J. Bielski (unpublished results).
  • Wardman P. Reduction Potentials of One-Electron Couples Involving Free Radicals in Aqueous Solution. Journal of Physical and Chemical Reference Data 1989; 18: 1637–1755
  • Lind J., Shen X., Merenyi G., Jonsson B. O. Determination of the Rate Constant of Self-Exchange of the O2/O2- Couple in Water by 18O/16O Isotope Marking. The Journal of the American Chemical Society 1989; 111: 7654–7655
  • Zahir K., Espenson J. H., Bakac A. Reactions of Polypyridylchromium(II) Ions with Oxygen: Determination of the Self-Exchange Rate Constant of O2/O2-. The Journal of the American Chemical Society 1988; 110: 5059–5060
  • Sutin N. Free Energies, Barriers, and Reactivity Patterns in Oxidation-Reduction Reactions. Accounts of Chemical Research 1968; 1: 225–231, and references therein

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.