Selection of eutectic systems in AI₂O₃–Y₂O₃ ceramics

Abstract

There are two eutectic reactions in the Al₂0₃–rich portion of the AI₂O₃-Y₂O₃ pseudo–binary system; one is the equilibrium A1₂0₃–YAG eutectic reaction at 1826%C, and the other is the metastable A1₂0₃–YAP eutectic reaction at 1702%C. Selection of the A1₂0₃–YAG and the A1₂0₃–YAP eutectics was examined in terms of cooling rate, nucleation temperature and maximum melt temperature. When the melt was cooled from 2100%C at any cooling rate, it always nucleated below the Al₂0₃–YAP eutectic temperature, therefore the Al₂0₃–YAP eutectic was selected. The Al₂0₃–YAG eutectic was selected when the melt was cooled from 1900%C at a cooling rate of less than 1 K s^-1. The selection of the two eutectic systems was determined by the nucleation temperature, although the maximum holding temperature of the melt and the cooling rate significantly affected the nucleation temperature. The structure of the melt, such as coordination of oxygen and chemical order when being heated to 2100%C may affect the nucleation behavior.

Key words:

• Eutectic Solidification
• Al₂0₃–YAG ceramics
• Selection of eutectic system
• Undercooling