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Organic Chemistry

Biosynthesis of Epoxydon and Related Compounds by Phyllosticta sp.

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Pages 409-413 | Received 22 Jul 1974, Published online: 09 Sep 2014
 

Abstract

The tetraketide origin of epoxydon I produced by Phyllosticta sp. is established by 13C NMR measurement on labelled epoxydons obtained from 1-13C- and 2-13C-acetate. The chlorinating mechanism of epoxydon to form non-enzymatically compound IV, V and VI was also confirmed by exposing epoxydon to the culture broth.

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